Would it still be ok to buy something online from Jeanswest, now that they are in administration, or is there too much of a risk that the order won't be fulfilled and the money won't be refunded?
Jeanswest - Buy online or too risky post admin announcement?
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any time anything goes into administration, only pay for goods where you get them in hand immediately.

Once a company enters administration the administers are actually legally obligated to fulfil the orders so you’re completely safe

See Buzztelco & Telecube mate…one day everything's normal, next day good bye to you and your internet.

Ozlegal

If you pay with a credit card you can always do a chargeback if they don't ship.
If they send you wrong size/model then it might get a bit more troublesome :P